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Creators/Authors contains: "Charles, Christopher"

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  1. Abstract. The Greater Cape Floristic Region (GCFR) ofSouth Africa is a biodiversity hotspot of global significance, and itsarcheological record has substantially contributed to the understanding ofmodern human origins. For both reasons, the climate and vegetation historyof southwestern South Africa is of interest to numerous fields. Currentlyknown paleoenvironmental records cover the Holocene, the lastglacial–interglacial transition and parts of the last glaciation but do notencompass a full glacial–interglacial cycle. To obtain a continuousvegetation record of the last Pleistocene glacial–interglacial cycles, westudied pollen, spores and micro-charcoal of deep-sea sediments from IODPSite U1479 retrieved from SW of Cape Town. We compare our palynologicalresults of the Pleistocene with previously published results of Pliocenematerial from the same site. We find that the vegetation of the GCFR, inparticular fynbos and afrotemperate forest, responds to precessional forcingof climate. The micro-charcoal record confirms the importance of fires inthe fynbos vegetation. Ericaceae-rich and Asteraceae-rich types of fynboscould extend on the western part of the Paleo-Agulhas Plain (PAP), whichemerged during periods of low sea level of the Pleistocene. 
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  2. Molecules containing short-lived, radioactive nuclei are uniquely positioned to enable a wide range of scientific discoveries in the areas of fundamental symmetries, astrophysics, nuclear structure, and chemistry. Recent advances in the ability to create, cool, and control complex molecules down to the quantum level, along with recent and upcoming advances in radioactive species production at several facilities around the world, create a compelling opportunity to coordinate and combine these efforts to bring precision measurement and control to molecules containing extreme nuclei. In this manuscript, we review the scientific case for studying radioactive molecules, discuss recent atomic, molecular, nuclear, astrophysical, and chemical advances which provide the foundation for their study, describe the facilities where these species are and will be produced, and provide an outlook for the future of this nascent field. 
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  3. Abstract Submarine groundwater discharge is increasingly recognized as an important component of the oceanic geochemical budget, but knowledge of the distribution of this phenomenon is limited. To date, reports of meteoric inputs to marine sediments are typically limited to shallow shelf and coastal environments, whereas contributions of freshwater along deeper sections of tectonically active margins have generally been attributed to silicate diagenesis, mineral dehydration, or methane hydrate dissociation. Here, using geochemical fingerprinting of pore water data from Site J1003 recovered from the Chilean Margin during D/V JOIDES Resolution Expedition 379 T, we show that substantial offshore freshening reflects deep and focused contributions of meteorically modified geothermal groundwater, which is likely sourced from a reservoir ~2.8 km deep in the Aysén region of Patagonia and infiltrated marine sediments during or shortly after the last glacial period. Emplacement of fossil groundwaters reflects an apparently ubiquitous phenomenon in margin sediments globally, but our results now identify an unappreciated locus of deep submarine groundwater discharge along active margins with potential implications for coastal biogeochemical processes and tectonic instability. 
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  4. Abstract A common conception of the deep ocean during ice age episodes is that the upper circulation cell in the Atlantic was shoaled at the Last Glacial Maximum compared to today, and that this configuration facilitated enhanced carbon storage in the deep ocean, contributing to glacial CO2draw‐down. Here, we test this notion in the far South Atlantic, investigating changes in glacial circulation structure using paired neodymium and benthic carbon isotope measurements from International Ocean Discovery Program Site U1479, at 2,615 m water depth in the Cape Basin. We infer changes in circulation structure across the last glacial cycle by aligning our site with other existing carbon and neodymium isotope records from the Cape Basin, examining vertical isotope gradients, while determining the relative timing of inferred circulation changes at different depths. We find that Site U1479 had the most negative neodymium isotopic composition across the last glacial cycle among the analyzed sites, indicating that this depth was most strongly influenced by North Atlantic Deep Water (NADW) in both interglacial and glacial intervals. This observation precludes a hypothesized dramatic shoaling of NADW above ∼2,000 m. Our evidence, however, indicates greater stratification between mid‐depth and abyssal sites throughout the last glacial cycle, conditions that developed in Marine Isotope Stage 5. These conditions still may have contributed to glacial carbon storage in the deep ocean, despite little change in the mid‐depth ocean structure. 
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